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- W2360643090 abstract "Polarized light microscopy,molar conductivity and UV-Vis absorption spectrum were used to study the aqueous solution properties of modified vat dyes,such as indanthrene blue RSN(RSN),indanthrene scarlet GG(GG) and dark blue BO(BO).The effects of the concentration,temperature and blending of dyes on the properties of molecular self-assembly were evaluated.The type of the aggregates and their formation mechanism were analyzed.The results show that the molecules were self-assembled into ordered aggregates with the function of aryl π-π conjunction and hydrogen bonds between sulfonic acid groups and polar solvent water. Sufonated indanthrene blue RSN and dark BO referred to as H-aggregates while sulfonated indanthrene scarlet GG belonged to J-aggregates.The molecular structures and introduced hydrophilic groups had an effect on the mode of self-assembly and the types of aggregates.In the certain concentration aqueous solutions,textures with strip or rod shapes were observed by polarized light microscopy with crossed polarizers and identified as lyotropic liquid crystal(LLC) phases.The uniformity of sulfonated vat dye molecular mixed self-assembly correlated with the concentration directly." @default.
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- W2360643090 date "2007-01-01" @default.
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- W2360643090 title "Research on Molecular Self-assembled Properties of Modified Vat Dyes" @default.
- W2360643090 hasPublicationYear "2007" @default.
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