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- W2360668575 abstract "Fine desulfurization of coking benzene was studied via Friedel-Crafts acylation reaction with acetic anhydride as acylating agent.Catalytic activity of several solid acids,such as MCM-41,HZSM-5,Mont-K10,and their supported catalysts was tested.We found that Mont-K10 had the highest catalytic activity,and its catalytic activity decreased with the increase of the ZnCl2 loading.The mechanism of acetylation catalyzed by solid acid was investigated by FT-IR technique.The results revealed that Lewis acid was the active site for this acylation reaction and the loading of ZnCl2 led to the increase in both the amount and the strength of acid sites.Under the optimum conditions,thiophene conversion rate reached 99.4%.After regeneration for three times,the catalytic activity was recovered and the conversion rate was still up to 90%,though the treatment capacity decreased to half." @default.
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- W2360668575 date "2012-01-01" @default.
- W2360668575 modified "2023-09-22" @default.
- W2360668575 title "Separating Thiophene from Coking Benzene by Friedel-Crafts Acylation Reaction over Solid Acids" @default.
- W2360668575 hasPublicationYear "2012" @default.
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