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- W2360736547 abstract "The SBS-g-MMA was synthesized based on styrene-butadiene-styrene block polymer(SBS) and methyl methacrylate(MMA).Under oxygen and nitrogen atmosphere condition,SBS-g-MMA thermal degradation process has been studied by using thermal analysis method.The results indicated that the SBS-g-MMA degradation included two steps under nitrogen atmosphere,the thermal degradation temperature approximately is 530~720 K in the first step and the second step is 720~830 K.The SBS-g-MMA degradation included three steps under oxygen atmosphere,the first step of thermal degradation temperature approximately is 477~597 K,the second step is 597~714 K and the third step is 714~774 K.By Comparison of the 39 species common mechanism function with Achar's method and Coats-redfern's method,it was obtained that average activation energy of the first step under nitrogen was 376.27 kJ/mol,the total mark function of the thermal degradation mechanism was g(a)=[-ln(1-α)]3,and frequency factor lnA=64.220.The differential function of the thermal degradation mechanism was f(a) =(1-α)[-ln(1-α)]-2/3,and frequency factor lnA=73.029.The thermal degradation process under O2 atmosphere was more complicated with little results." @default.
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- W2360736547 date "2009-01-01" @default.
- W2360736547 modified "2023-09-24" @default.
- W2360736547 title "Thermal Degradation Kinetics and Synthesis Study about SBS-g-MMA" @default.
- W2360736547 hasPublicationYear "2009" @default.
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