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- W2360948420 abstract "The systems In-Sb and Sn-Te are similar to each other in that both contain a compound of definite composition and no range of solid solution. These two systems have been investigated by various authors by emf measurements on cells represented by In(1)|InBr(l)|In-Sb(l), (Ⅰ) In(l)|InCl(l)|Sb(s)+InSb(s), (Ⅱ) and Sn(l)|SnCl_2(l)|Te(s)+SnTe(s). (Ⅲ) Taking the In-Sb system as an example, we have shown in this paper that the activity data on In-Sb melts and the free energy of formation of the intermetallic compound InSb(s), which were evaluated from the emf of the In-Sb cells (Ⅰ) and (Ⅱ) respectively, can be correlated with each other by the use of the phase diagram and a modified Gibbs-Duhem equation. In a like manner, the activities of Sn in Sn-Te melts of various compositions have been calculated from the free energy of formation of Sn-Te(s) obtained from the emf of the Sn-Te cell (Ⅲ). It is suggested that the method of treatment developed in this paper may be applied to other binary systems involving an intermetallic compound where sufficient data are available." @default.
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- W2360948420 date "1964-01-01" @default.
- W2360948420 modified "2023-09-23" @default.
- W2360948420 title "CORRELATION OF THERMODYNAMIC DATA WITH PHASE DIAGRAMS IN In-Sb AND Sn-Te SYSTEMS" @default.
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