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- W2361005717 abstract "The formation kinetics study of gasoline sulfocompounds,including mercaptan and thiophenic compounds with their boiling point in the range of gasoline fraction,from the reaction of FCC gasoline olefin with H2S over fluid catalytic cracking catalyst in the temperature range of 400-500℃,in which the internal and external diffusion effects could be eliminated,was carried out in a small fixed fluidized bed(FFB) unit.On the basis of cracking reaction of FCC gasoline without H2S,eliminating effect of the temperature on the olefin catalytic transformation,the kinetic model of power-law type for describing the formation of gasoline sulfocompounds from the reaction of olefin with H2S was developed.The activation energies of the formation of thiophenic compounds and total sulfocompounds were 28810 J/mol and 25376 J/mol,respectively,for which the reaction orders of relative gasoline olefin were 0.38 and 0.36,and the reaction orders of H2S were 0.22 and 0.27,respectively.Residual error distribution and statistical test showed that the developed models were acceptable and reliable,which actually reflected the characters of the formation of gasoline sulfocompounds." @default.
- W2361005717 created "2016-06-24" @default.
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- W2361005717 date "2009-01-01" @default.
- W2361005717 modified "2023-09-26" @default.
- W2361005717 title "FORMATION KINETICS OF SULFUR COMPOUNDS IN FCC GASOLINE" @default.
- W2361005717 hasPublicationYear "2009" @default.
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