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- W2361329494 abstract "This paper describes experimental results for the mediated electrooxidation of 11α-hydroxy-16, 17α-epoxy-progestron into 11-keto-16, 17α-epoxy-progestron. The organic substrateis chemically oxidated by hexavalent chromium in a CH_2Cl_2/H_2O (4 mol/L H_2SO_4) system at24~26℃, the presence of a phase transfer agent (tetrabutylammonium hydrogen sulphate)greatly accelerated the reaction. Used solutions of chromium could be regenerated at Pt anodein 4 mol/L sulphuric acid media with Ag~+ as catalyst. The current efficiency was over 70%and the chemical yield was over 95%. The mediated system may be recycled. A probablemechanism of this reaction is suggested." @default.
- W2361329494 created "2016-06-24" @default.
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- W2361329494 date "1990-01-01" @default.
- W2361329494 modified "2023-09-23" @default.
- W2361329494 title "Indirect Electrooxidation of 11α-Hydroxy-16, 17α-epoxy-progestron" @default.
- W2361329494 hasPublicationYear "1990" @default.
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