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- W2361477939 abstract "The precursor NH4CoPO4 was synthesized firstly via the solid-state reaction at low-heating temperature with lithium hydroxide,ammonium dihydrogen phosphate and cobalt acetate as raw materials in the present of PEG-400.Then the nano-crystallite LiCoPO4 powder was successfully obtained via the solid-state reaction of the prepared precursor at high temperature.The products were characterized with XRD,FT-IR and SEM,and the results show that,in the high temperature solid-state reaction,the precursor NH4CoPO4 is quickly reacted to form amorphous intermediates.The formation of LiCoPO4 via solid phase reaction undergoes a series of complex kinetic competitive process.The Co2P2O7,Li3PO4 and LiCoPO4 accrete in the products,and the transform reaction of Li3PO4 follows the index nucleation reaction mechanism with the active energy of 41.8 kJ·mol-1 which is the control step of the solid-state reaction.The formation reactions of LiCoPO4 and Co2P2O7 can be described by power law mechanism model,and there exists a transform reaction transforming Co2P2O7 to LiCoPO4.The above transforming reaction agrees with the Avrami-erofeev mechanism model of reaction controlled by the phase-boundary reaction of constant rate nucleation and two-dimensional nuclear growth with the reaction order n=3.Furthermore,the transform reaction from Co2P2O7 to LiCoPO4 is promoted by high temperature,but the size of the sample particles increases,which will impede further proceeding of the reaction." @default.
- W2361477939 created "2016-06-24" @default.
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- W2361477939 date "2010-01-01" @default.
- W2361477939 modified "2023-09-23" @default.
- W2361477939 title "The Reaction Kinetics of Synthesis of Nano-Crystallite LiCoPO_4 from Precursor via Solid-State Reaction" @default.
- W2361477939 hasPublicationYear "2010" @default.
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