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- W2361497498 abstract "MxOy-ZrO2-Al2O3 solid acid catalysts is prepared by sol-gel method.The catalytic property of MxOy-ZrO2-Al2O3 is evaluated by catalytic conversion of fructose to 5-hydroxymethylfurfural(5-HMF).The results indicate that La2O3-ZrO2-Al2O3 shows superior catalytic activity comparing with other MxOy-ZrO2-Al2O3 solid acid catalysts.The yield of 5-HMF can reach up to 74.91% with 79.9% of selectivity to 5-HMF when the degradation of fructose is catalyzed by La2O3-ZrO2-Al2O3 in dimethylsulfoxide for 75 minutes at 120℃.Further studies show that the crystal structure of La2O3-ZrO2-Al2O3 strongly affects its catalytic activity.The catalytic activity is markedly decreased when the crystal structure turns from higher crystallization degree to amorphous.In addition,La2O3-ZrO2-Al2O3 also exhibits excellent recycle ability.The catalyst can be recycled 2 times without loss of catalytic activity." @default.
- W2361497498 created "2016-06-24" @default.
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- W2361497498 date "2012-01-01" @default.
- W2361497498 modified "2023-09-28" @default.
- W2361497498 title "Preparation of 5-hydroxymethylfurfural from fructose catalyzed by solid acid catalysts MxOy-ZrO_2-Al_2O_3" @default.
- W2361497498 hasPublicationYear "2012" @default.
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