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- W2361658512 abstract "[Ru6(μ-O2CCH3)12(CH3OH)2(HCOO)2][Ru2(μ-O2CCH3)4(H2O)2](PF6)2·2H2O(with mixed valence Ru2(Ⅱ,Ⅲ))was synthesized by two-step reactions.Firstly,heat Ru2(O2CCH3)4Cl in methanol under argon to get a brown red intermediate,then treat the intermediate with methanol aqueous solution in the presence of Ag2SO4 and NH4PF6 to get the title compound.The compound was characterized by elemental analysis,IR spectra,thermogravimetric analysis,cyclic voltammetry,and X-ray single crystal structure analysis.Its crystal belongs to monoclinic system with P21/n space group,in which a=0.853 62(14)nm,b=1.195 89(19)nm,c=3.664 2(6)nm,β=92.316(3)° and Z=2.Each structure element of the crystal contains two different match ions,[Ru2(μ-O2CCH3)2(H2O)2]+ and [Ru6(μ-O2CCH3)12(CH3OH)2(HCOO)2]+.The former is a dinuclear ruthenium match ion.The latter is a six nuclear ruthenium match ion in coordination with methanol and bridge with formic acid.As independent components,the two elements were connected by hydrogen bond to form a three-dimensional supramolecular network.The electrochemical property of ruthenium complex has been studied by means of cyclic voltametry,the results show that electron transfer between Ru(Ⅱ)and Ru(Ⅲ)in electrolysis is quasi-reversible process.CCDC:793726." @default.
- W2361658512 created "2016-06-24" @default.
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- W2361658512 date "2011-01-01" @default.
- W2361658512 modified "2023-09-25" @default.
- W2361658512 title "Synthesis,Crystal Structure and Electrochemical Properties of a Mixed Valence Ruthenium Complex" @default.
- W2361658512 hasPublicationYear "2011" @default.
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