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- W2361730025 abstract "A palladium-catalyzed regio- and diastereoselective diarylation of glycals and pseudoglycals, which is a kind of Heck-Suzuki arylation, is described. A wide range of arylboronic acids reacted under these conditions smoothly. Selectivity was C1-C2(α,α) in the case of glycals but C2-C3(β,β) for pseudoglycals. Quantum chemical analysis has been carried out to establish the reaction mechanism, which may involve Pd(II)/Pd(O). TEMPO plays a key role in the formation of diaryl glycoside due to its radical nature." @default.
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- W2361730025 date "2015-07-23" @default.
- W2361730025 modified "2023-10-07" @default.
- W2361730025 title "TEMPO-Promoted Domino Heck–Suzuki Arylation: Diastereoselective <i>Cis</i>-Diarylation of Glycals and Pseudoglycals" @default.
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- W2361730025 doi "https://doi.org/10.1021/acs.orglett.5b01722" @default.
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