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- W2361965536 abstract "Ni-P and its nano-CeO_2 doped coating were electrolessly prepared in acidic condition,and their microstructure and anti-corrosion property were studied and compared.Scanning electronic microscopy(SEM),transmission electronic microscopy(TEM),X-ray diffraction spectrometer(XRD)and differential scanning calorimeter(DSC)were used to examine surface morphology and microstructure of coatings.The results showed that Ni-P coating had partial amorphous structure mixed with nano-crystals,while the Ni-P/CeO_2 coating had perfect amorphous structure.Upon heating,Ni3P precipitation and Ni crystallization took place in both coatings but at different temperatures of phase change.In addition,the Ni-P/CeO_2 coating had sintered phase of NiCe2O4 spinels.The anti-corrosion property and passivity were improved in the CeO_2-doped coating because it was less liable to undergo localized corrosion and had a slower corroding rate than its CeO_2-free counterpart.During the co-deposition process,some Cen+(n=3,4)ions might be adsorbed to the metal/solution electrical double layer and hinder nickel deposition.Ni-P/CeO_2 coating's perfect amorphous structure was probably due to the hindered crystal-typed deposition of nickel and the promoted deposition of phosphorous." @default.
- W2361965536 created "2016-06-24" @default.
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- W2361965536 date "2008-01-01" @default.
- W2361965536 modified "2023-09-24" @default.
- W2361965536 title "Effect of nano-CeO_2 doping on microstructure and corrosion of Ni-P electroless coating" @default.
- W2361965536 hasPublicationYear "2008" @default.
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