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- W2361987911 abstract "Broadband ac dielectric techniques in the 5Hz - 10GHz frequency range and thermally stimulated depolarization currents (TSDC), polarization currents (TSPC) and de conductivity techniques in the 77 - 300 K temperature range are used to measure the dielectric relaxation spectra of water confined in small volumes of mesoscopic dimensions in three different systems: vycor glasses, Na-13X zeolites and poly(hydroxyethyl acrylate) (PHEA) hydrogels. A fraction of water of about 0.02 - 0.03 (w jw) in vycor glass, 0.30 in zeolites and 0.20 - 0.30 in PHEA does not contribute by reorientation to the dielectric spectra neither crystallizes upon coolig. The rotational mobility of water in excess to that fraction is restricted compared to that of bulk water. In the zeolites two distinct dielectric relaxations of water in the supercages and the 13-cages respectively are observed. In vycor glass evidence is obtained for a glass (or glass-like) transition of water in the primary hydration layer at about 170 K. 1.1ntroduction" @default.
- W2361987911 created "2016-06-24" @default.
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- W2361987911 date "1994-01-01" @default.
- W2361987911 modified "2023-09-23" @default.
- W2361987911 title "STRUCTURE AND DYNAMIC PROPERTIES OF WATER CONFINED IN SMALL VOLUMES" @default.
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