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- W2362202005 abstract "Conductive detection can determine the HCl loss amount and rate continuously during the drying process,which is an effective method to study the thermal-degradation behavior of chlorinated natural rubber(CNR) at low temperature.Fresh CNR,prepared by a new latex method,is dried at a certain temperature with the existence of nitrogen.During the drying process,the dehydrochlorination process happens,which can be divided into induction,constant rate and low speed stages.The kinetics parameters of constant rate and low speed periods were analyzed by Friedman equation.The results show that the dehydrochlorination processes are zero order reaction and first order reaction for constant rate and low speed periods respectively,and the corresponding activation energies are 26.65,36.79 kJ/mol respectively.There is little HCl produced during the drying process at 80 ℃,but no negative effect on CNR quality.Therefore the ideal drying temperature is 80 ℃ below." @default.
- W2362202005 created "2016-06-24" @default.
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- W2362202005 date "2012-01-01" @default.
- W2362202005 modified "2023-09-23" @default.
- W2362202005 title "Dehydrochlorination kinetics of chlorinated natural rubber prepared by latex method during drying process" @default.
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