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- W2362583098 abstract "Temperature-sensitive association behavior of polymer PAVD of sodium 2-acrylamido-2-methylpropane sulphonate(NaAMPS),N-vinylcaprolactam(VCL)and divinyl benzene(DVB)in aqueous solution was investigated by visible spectrophotometer,variable-temperature 1 H-NMR and rheometer from cloud point and viscosity changes.The influence of molecular structure of PAVD on temperature-sensitive association was revealed.The results from monitoring phase change process by visible spectrophotometer and variable-temperature 1 H-NMR show that the higher the VCL content,the lower the cloud point.The results from variable-temperature 1 H-NMR also show that as temperature rises,methylene segments of VCL side chain in PAVD become hydrophobic,producing hydrophobic association.The rheological tests show that only when the VCL content in PAVD is within a certain range,it would appear obvious thermosensitive thickening phenomenon.The higher the VCL content,the lower the critical thickening temperature,and temperature-sensitive thickening phenomenon is more significant.The thermosensitive association phenomenon was analysed by comparative analysis of the critical thickening temperature and lower critical solution temperature(LCST)." @default.
- W2362583098 created "2016-06-24" @default.
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- W2362583098 date "2014-01-01" @default.
- W2362583098 modified "2023-09-24" @default.
- W2362583098 title "Effect of Polymer P(NaAMPS-VCL-DVB)Molecular Structure on Temperature-sensitive Association Behavior" @default.
- W2362583098 hasPublicationYear "2014" @default.
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