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- W2362686816 abstract "Two new nickel complexes with a new 1,2-dithiolate ligand, (Bu4N)2[Ni(nbdt)2] (1) and (Bu4N)[Ni(nbdt)2] (2) (nbdt=4-nitro-benzene-1,2-dithiolate), have been synthesized and characterized by X-ray single-crystal struc- ture determination, cyclic voltammetry, ESR, UV/Vis spectra and magnetic susceptibility measurements. Complex 2 was obtained by oxidation of complex 1 with I2. The crystal structure determination reveals that the central Ni atoms in complexes 1 and 2 are in slightly distorted square-planar coordination environment. The cyclic voltam- metric studies show that there are two oxidation peaks at 0.15 and 0.85 V for complex 1. The antiferromagnetic interaction dominates the magnetic properties in complex 2. CCDC: 287714; 287715." @default.
- W2362686816 created "2016-06-24" @default.
- W2362686816 creator A5055085150 @default.
- W2362686816 date "2006-01-01" @default.
- W2362686816 modified "2023-09-23" @default.
- W2362686816 title "Syntheses, Structures and Properties of Nickel Complexes with 4-nitro-benzene-1,2-dithiolate Ligand" @default.
- W2362686816 hasPublicationYear "2006" @default.
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