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- W2362936856 abstract "Three kinds of novel N-heterocyclic carbene allyl palladium complexes(Catalyst 1,2 and 3) were synthesized.Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane(MAO) in toluene.The effects of reaction temperature,the molar ratio of aluminum to palladium and the molar ratio of norbornene to palladium on the catalytic activity and the property of polymer were investigated for catalyst 2.The results show that the catalytic systems display high catalytic efficiency.The highest catalytic efficiency is 3.2×107 g PNE/(mol Pd·h).The resultant polymer is of excellent heat-resistant property.The decomposition is over 400 ℃.According to FT-IR spectra,the polymerization mechanism is vinyl-addition type polymerization." @default.
- W2362936856 created "2016-06-24" @default.
- W2362936856 creator A5089813280 @default.
- W2362936856 date "2008-01-01" @default.
- W2362936856 modified "2023-09-23" @default.
- W2362936856 title "Polymerization of Norbornene via Allyl Palladium-Based Complexes Bearing o-Hydroxyarl N-Heterocyclic Carbenes [C,O] Ligands/MAO" @default.
- W2362936856 hasPublicationYear "2008" @default.
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