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- W2363214991 abstract "Activated carbon as a carrier,ruthenium chloride as the active precursor preparation for Ru/C catalyst using supercritical CO2 fluid deposition method.The catalytic activity of catalysts were studied by reaction of glucose hydrogenation to sorbitol.The effects of preparation condition for Ru/C catalyst,ie,temperature,the amount of CO2 and the amount of reducing agent KBH4,on activity of the Ru/C catalysts were investigated by orthogonal experiment.Ru/C catalyst samples were investigated by IR and scanning electron microscopy(SEM).The results indicated that properties of the Ru/C catalysts were remarkably affected by temperature.The best process conditions of Ru/C catalyst was that activate carbon was 0.6000 g,RuCl3 was 0.1000 g,the amount of methanol cosolvent was 0.5 mL,the temperature was 60 ℃,CO2 volume was 40 mL,the amount of reducing agent KBH4 was 0.10 g.The best catalytic activity was 28.3 mmol/(min·g) which was 1.89 times than the traditional preparation of the catalyst.RuCl3 combination with the particulate carbon was not a simple physical adhesion,but rather a chemical reaction occurs,the formation of the Ru/C catalyst kept the original surface morphology of carbon particles,ruthenium of distribution was very uniform." @default.
- W2363214991 created "2016-06-24" @default.
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- W2363214991 date "2011-01-01" @default.
- W2363214991 modified "2023-09-28" @default.
- W2363214991 title "The Research of Ru/C Catalyst in Supercritical Fluids" @default.
- W2363214991 hasPublicationYear "2011" @default.
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