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- W2363695376 abstract "The thermal degradation behaviors of two chlorinated para-aromatic polyamide(Cl-PPTA)thin films and poly-p-phenylene terephthamide(PPTA)powder were measured by thermogravimetry-Fourier transform infrared spectrum(TG-FTIR)and pyrolysis-gas chromatography/mass spectrometry(Py-GC/MS).The characteristic temperature of three samples in air and nitrogen atmosphere was obtained by TG analysis,which indicated that Cl-PPTA had excellent thermal stability in air condition and had better higher char residue(CR)than PPTA in nitrogen condition.The gases released by the pyrolysis of Cl-PPTA in air were mainly HCN,CO,CO2,NO2 and H2O,and the absorption peaks of CO2 were the strongest.With IR analysis on the CR of Cl-PPTA films under high temperature treatment in nitrogen atmosphere,the carbonyl absorption peak became weak and the new end groups or the function groups appeared.Results of Py-GC/MS in different temperature showed that the main pyrolysates were CO2 and benzene.The Py-GC/MS of Cl-PPTA greatly changed due to the changes of pyrolysis temperature.And all these pyrolysates can help to study the suggested pathway for the formation of the major degradation products of Cl-PPTA film." @default.
- W2363695376 created "2016-06-24" @default.
- W2363695376 creator A5018761366 @default.
- W2363695376 date "2015-01-01" @default.
- W2363695376 modified "2023-09-26" @default.
- W2363695376 title "Study on the Thermal Degradation Process of Chlorinated Para-aromatic Polyamide by TG-FTIR and Py-GC/MS" @default.
- W2363695376 hasPublicationYear "2015" @default.
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