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- W2364232443 abstract "Two novel dicobalt complexes, [CoII/III2(HImbm)(bipy)4](ClO4)3·2H2O (1) and [CoIII/III2(HImbm)(bipy)4](ClO4)4·CH3OH·4H2O (2) (H3Imbm = 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid; bipy = 2,2′-bipyridine), have been synthesized and characterized. Single-crystal X-ray analyses revealed that both 1 and 2 featured a similar HImbm-bridged dicobalt unit, except for oxidation state assignments of CoII/CoIII mixed-valence in 1 and CoIII/CoIII equal valence in 2. EB-DNA fluorescence quenching study of 1 and 2 suggest moderate intercalative binding modes between the compounds and DNA. Magnetic properties have been investigated for 1 and the result is in agreement with the behavior of unquenched spin-orbit coupling of six-coordinated high-spin Co(II) ions." @default.
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- W2364232443 date "2016-02-22" @default.
- W2364232443 modified "2023-09-25" @default.
- W2364232443 title "Synthesis, Structure, DNA Binding, and Magnetic Properties of Dicobalt (II/III, III/III) Complexes Based on 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic Ligand" @default.
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- W2364232443 doi "https://doi.org/10.1080/15533174.2015.1137016" @default.
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