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- W2364241913 abstract "The catalytic reaction kinetics of water- soluble manganese porphrin complex, MnⅢ(TMPyP) with NaOCl of room temperature at different pH has been investigated by the rapid - mixing stopped - flow techniques. The reaction mechanism was proposed. At lower pH values HOCl was the main oxidant and the short - lived intermediate (1) could not be fully formed, whereas the relatively stable intermediate (2) was produced. At higher pH OCl- was the main oxidant and high - valent oxomanganese(Ⅴ) porphyrin (1) was fully formed, which then decayed to oxoMn(Ⅳ) . It was shown by using reducing substrates that the high -valent oxomanganese(Ⅴ) porphyrin was the reactive complexes." @default.
- W2364241913 created "2016-06-24" @default.
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- W2364241913 date "2000-01-01" @default.
- W2364241913 modified "2023-09-25" @default.
- W2364241913 title "Study for the Reaction Mechanism of Mn~III (TMPyP)-NaOCl System" @default.
- W2364241913 hasPublicationYear "2000" @default.
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