Matches in SemOpenAlex for { <https://semopenalex.org/work/W2364291651> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2364291651 abstract "The reactivity of the hydroxyl group of the syn diisopropyl 1-bromo-2-hydroxy-2-(p-methoxyphenyl)ethylphosphonate was studied. Due to the electron-withdrawing effects from both the phosphonate group and the electronegative bromine atom, the electron density around the oxygen atom of the hydroxyl group was lowered, which resulted in the acidity increase of the hydroxyl proton and nucleophilicity decrease of the corresponding alkoxide anion under basic conditions. Therefore, unusual reactivity dealing with Mitsunobu dehydation reaction and esterification were found. And also, the steric hindrance arisen from the formation of hydrogen bond and the bulky phosphonate group should partly account for the poor reactivity of the hydroxyl group with acyl chlorides." @default.
- W2364291651 created "2016-06-24" @default.
- W2364291651 creator A5072261264 @default.
- W2364291651 date "2004-01-01" @default.
- W2364291651 modified "2023-09-23" @default.
- W2364291651 title "Study on the Reactivity of Hydroxyl Group of the syn Diisopropyl 1-Bromo-2-hydroxy-2-(p-methoxyphenyl)ethylphosphonate" @default.
- W2364291651 hasPublicationYear "2004" @default.
- W2364291651 type Work @default.
- W2364291651 sameAs 2364291651 @default.
- W2364291651 citedByCount "0" @default.
- W2364291651 crossrefType "journal-article" @default.
- W2364291651 hasAuthorship W2364291651A5072261264 @default.
- W2364291651 hasConcept C112887158 @default.
- W2364291651 hasConcept C142724271 @default.
- W2364291651 hasConcept C155647269 @default.
- W2364291651 hasConcept C161790260 @default.
- W2364291651 hasConcept C178790620 @default.
- W2364291651 hasConcept C178907741 @default.
- W2364291651 hasConcept C185592680 @default.
- W2364291651 hasConcept C201194858 @default.
- W2364291651 hasConcept C204787440 @default.
- W2364291651 hasConcept C2776640939 @default.
- W2364291651 hasConcept C2776910235 @default.
- W2364291651 hasConcept C2777626080 @default.
- W2364291651 hasConcept C2778839380 @default.
- W2364291651 hasConcept C2780263894 @default.
- W2364291651 hasConcept C32909587 @default.
- W2364291651 hasConcept C71924100 @default.
- W2364291651 hasConceptScore W2364291651C112887158 @default.
- W2364291651 hasConceptScore W2364291651C142724271 @default.
- W2364291651 hasConceptScore W2364291651C155647269 @default.
- W2364291651 hasConceptScore W2364291651C161790260 @default.
- W2364291651 hasConceptScore W2364291651C178790620 @default.
- W2364291651 hasConceptScore W2364291651C178907741 @default.
- W2364291651 hasConceptScore W2364291651C185592680 @default.
- W2364291651 hasConceptScore W2364291651C201194858 @default.
- W2364291651 hasConceptScore W2364291651C204787440 @default.
- W2364291651 hasConceptScore W2364291651C2776640939 @default.
- W2364291651 hasConceptScore W2364291651C2776910235 @default.
- W2364291651 hasConceptScore W2364291651C2777626080 @default.
- W2364291651 hasConceptScore W2364291651C2778839380 @default.
- W2364291651 hasConceptScore W2364291651C2780263894 @default.
- W2364291651 hasConceptScore W2364291651C32909587 @default.
- W2364291651 hasConceptScore W2364291651C71924100 @default.
- W2364291651 hasOpenAccess W2364291651 @default.
- W2364291651 hasRelatedWork W1974763697 @default.
- W2364291651 hasRelatedWork W1987425923 @default.
- W2364291651 hasRelatedWork W2041034763 @default.
- W2364291651 hasRelatedWork W2043412480 @default.
- W2364291651 hasRelatedWork W2055206348 @default.
- W2364291651 hasRelatedWork W2062730008 @default.
- W2364291651 hasRelatedWork W2069856598 @default.
- W2364291651 hasRelatedWork W2070621769 @default.
- W2364291651 hasRelatedWork W2088038191 @default.
- W2364291651 hasRelatedWork W2092341884 @default.
- W2364291651 hasRelatedWork W2124304433 @default.
- W2364291651 hasRelatedWork W2188160493 @default.
- W2364291651 hasRelatedWork W2368015245 @default.
- W2364291651 hasRelatedWork W2925050801 @default.
- W2364291651 hasRelatedWork W2950271768 @default.
- W2364291651 hasRelatedWork W2950753325 @default.
- W2364291651 hasRelatedWork W2951348931 @default.
- W2364291651 hasRelatedWork W2952976211 @default.
- W2364291651 hasRelatedWork W3029633811 @default.
- W2364291651 hasRelatedWork W613867442 @default.
- W2364291651 isParatext "false" @default.
- W2364291651 isRetracted "false" @default.
- W2364291651 magId "2364291651" @default.
- W2364291651 workType "article" @default.