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- W2364370382 abstract "The influences of sulfurization of Mo on hydrocracking of iso-propylbenzene-D12,sulfurization of Ni(NO3)2 on hydrocracking of tert-butylbenzene and butylbenzene,and sulfurization of dispersed catalyst with Ni(NO3)2 as the main component on hydrocracking of two atmospheric residues were examined in the batch reactor.The exchange of branch chain hydrogen in iso-propylbenzene-D12 molecule with atmospheric hydrogen was prompted when Mo was used.The exchange of hydrogen on aromatic ring with atmospheric hydrogen was faster when Mo was sulfurized.The sulfurization of Ni(NO3)2 had the same influence on the exchange of hydrogen in tert-butylbenzene and butylbenzene molecules with atmospheric hydrogen.The results were different according to the molecular structure of reactants.As regards the reactants which were not easy to perform radical thermal cracking reactions,such as iso-propylbenzene and tert-butylbenzene,the sulfurization of catalyst prompted their hydrogenolysis cracking reaction and condensation reaction.Different from tert-butylbenzene,the radical thermal cracking reaction and the hydrogenolysis cracking reaction of butylbenzene were restricted,while the condensation reaction was prompted with the sulfurization of catalyst.On slurry bed hydrocracking of residues,the effect of sulfurization catalyst was similar to that on butylbenzene,that is,the cracking reaction was restricted and the condensation reaction was prompted.Therefore,the sulfurazation process for dispersed catalyst in hydrocracking of residue may be not a necessary procedure." @default.
- W2364370382 created "2016-06-24" @default.
- W2364370382 creator A5071082922 @default.
- W2364370382 date "2009-01-01" @default.
- W2364370382 modified "2023-09-26" @default.
- W2364370382 title "INFLUENCE OF SULFURIZATION OF DISPERSED CATALYST ON SLURRY BED HYDROCRACKING" @default.
- W2364370382 hasPublicationYear "2009" @default.
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