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- W2364374292 abstract "This may be the first report for producing hydrogen by electrolysis of local coal slurries in China.With Pt-/Ti and Pt-Ir/Ti(1∶2) electrodes prepared in the laboratory as the working electrodes,the influences of different electrolytic conditions,including the concentration of coal slurries and of sulfuric acid,temperature,kinds of electrodes and coal,and the catalysts such as Ce4+,Fe(CN)3-6,Fe3+ and Fe2+/Fe3+ in the solution on the hydrogen production were studied.The iridium content in the electrode affected the electrochemical performance of the coal and adding iron(Ⅲ) and iron(Ⅱ) in the coal slurry significantly increased the average current densities developed in the coal electrolytic cell.The maximum current efficiency found in the electro-oxidation of coal on a Pt-Ir/Ti(1∶2) electrode was 99.7% for H2 generation with 19.7 mL/(cm2·h) hydrogen produced.Anode gas analysis indicated that the main component is CO2 with trace CO.Some low hydrocarbon byproducts with lower boiling point were observed.The amount of CO2 was only 1/20-1/10 in volume of H2 produced,which would decrease the ability to cause more greenhouse effect." @default.
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- W2364374292 date "2007-01-01" @default.
- W2364374292 modified "2023-09-27" @default.
- W2364374292 title "Study of producing hydrogen by electrolysis of coal slurries" @default.
- W2364374292 hasPublicationYear "2007" @default.
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