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- W2364391386 abstract "Di-Grignard reagent BrMg(CH_2)_4MgBr can reductively cleave the S-S bond of two molecules of μ-S_2Fe_2(CO)_6 to give a double Fe-S cluster core intermediate A which contains a bridging butylene group. Reactions of A with alkyl halides, chloromethyl methyl ether, chloroketones, chlo- roesters or acyl chlorides in situ give ten structurally novel butylene-bridged double Fe-S core com- plexes B. For all the complexes B, the structures were confirmed by IR, ~1H NMR and elemental analysis while the conformers of some complexes B were deduced based on related ~1H NMR data. In addition, for Z=Me the structure and conformation of the complex B have been firmly established by an X-ray diffraction technique." @default.
- W2364391386 created "2016-06-24" @default.
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- W2364391386 date "1988-01-01" @default.
- W2364391386 modified "2023-09-23" @default.
- W2364391386 title "Syntheses, structures and conformation of butylene-bridged butterfly-shaped Fe-S cluster complexes" @default.
- W2364391386 hasPublicationYear "1988" @default.
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