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- W2364403736 abstract "the thermodynamics of axial coordination reaction of Co(Ⅱ) 2,9,16,23 tetracaboxyph thalocyanine with 2 mercaptoethanol in aqueous and with thiophenol in DMSO were studied. It was found that the centre metal ion Co(Ⅱ) was reduced to Co(Ⅰ). Coordination number and equilibrium constants of axial coordination reaction were measured by visible spectra techniques and the method of Miller Dorough. The changes of standard molar enthalpies Δ r H m and standard molar entropies Δ r S m of reaction were obtained from the plots of ln K a vs 1/ T . The influence of temperature was discussed." @default.
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- W2364403736 date "1999-01-01" @default.
- W2364403736 modified "2023-09-25" @default.
- W2364403736 title "THERMODYNAMIC STUDIES ON THE AXIAL COORDINATION REACTION OF Co-2,9,16,23-TETRACABOXYPHTHALOCYANINE WITH 2-MERCAPTOETHANOL AND THIOPHENOL" @default.
- W2364403736 hasPublicationYear "1999" @default.
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