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- W2364441520 abstract "The △Gm(T) and configurational entropy(Sm) of Pt,Rh,Pd alloy were calculated according to the relationship between the electronic structure of Pt,Rh,Pd,catalytic activity and thermodynamics under the standard condition.The formation condition of PtRhPd solid solution was inferred in the ammoxidation at 870 ℃.The results of computation were as follows:△Gm(T) PtRh=-3 500.520,△Gm(T) RhPd=-3 229.340,△Gm(T) PtPd=-3 941.560.The conditions of platinum recovery and PtPd solid solution formation in the ammonia oxidation were studied.It was found that PtPd solid solution of the gauze surface was formed at the temperature 300 K and could catalyze the ammonia oxidation.The surface morphologies of DEC product and traditional binary gauze were characterized by FESEM." @default.
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- W2364441520 date "2012-01-01" @default.
- W2364441520 modified "2023-09-25" @default.
- W2364441520 title "Researches on thermodynamics of PtRhPd alloy in ammonia oxidation" @default.
- W2364441520 hasPublicationYear "2012" @default.
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