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- W2364458757 abstract "The electrocatalytic activity of Ti/PbO2,graphite and platinum electrodes for the electrooxidation of p-methylphenol was studied by linear sweeping voltammetry and galvanostatic electrolysis in an electrolytic cell without diaphragm.The conversion,degradation rate,reaction mechanism and rate determining steps of p-methylphenol at the three kinds of electrodes were explored by determinations of p-methylphenol and intermediates in the electrolyte before and after electrolysis.The experimental results indicate that Ti/PbO2 electrode with a high activity can effectively oxidize and remove p-methylphenol;graphite electrode can also oxidize p-methylphenol,but its removal ability was poor;platinum electrode can only oxidize p-methylphenol to hydroquinone in the electrolytic time of 3 h;p-methylphenol can not be oxidized completely.The mechanism of the electrooxidation degradation of p-methylphenol may be p-methylphenol→p-hydroxy-benmethanol→p-hydroxybenzaldehyde→p-hydroxybenzoic acid→hydroquinone→benzoquinone→maleic acid→oxalic acid,and the final product is CO2.The electrooxidation reactions of hydroquinone and maleic acid are the rate determining steps for Ti/PbO2 electrode,while the electrooxidation reaction of hydroquinone is a rate determining step for graphite electrode." @default.
- W2364458757 created "2016-06-24" @default.
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- W2364458757 date "2008-01-01" @default.
- W2364458757 modified "2023-09-25" @default.
- W2364458757 title "Electrooxidation of p-Methylphenol at Different Catalyst Electrodes" @default.
- W2364458757 hasPublicationYear "2008" @default.
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