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- W2364656678 abstract "The ZSM-5 containing framework iron and vanadium ( n (Fe)/ n (V)=1) were hydrothermally synthesized and characterized by XRD, SEM, IR, DTA and ESR. The results of XRD indicate that the introducing of heteroatoms changed the size of the unit cell. The SEM photographs show that the granule size of the samples obviously increase with the increasing of heterotomic concentration. The investigations of IR and ESR verified that Fe 3+ and V 4+ enter to the framework of ZSM-5 ,and Fe 3+ got into the framework more easily than V 4+ as increasing heterotomic concentration, however, a party of V 4+ may be present in oxide type. DTA reveals that the structure of double heterotomic ZSM-5 would not be varied at 900 ℃ and possesed good thermostability. The ZSM-5 containing framework iron and vanadium exhibit more activity and selectivity than the single heterotomic ZSM-5 containing framework iron or vanadium in the reaction of ethylbenzene oxidation dehydrogen. The conversion of ethylbenzene and the selectivity of styrene are respectively 26.7% and 90.5% when the reaction is stable." @default.
- W2364656678 created "2016-06-24" @default.
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- W2364656678 date "2002-01-01" @default.
- W2364656678 modified "2023-09-23" @default.
- W2364656678 title "Synthesis and Characterization of ZSM-5 Containing Framework Iron and Vanadium and Its Catalytic Performance" @default.
- W2364656678 hasPublicationYear "2002" @default.
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