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- W2364658905 abstract "The asymmetric reduction of aromatic ketones catalyzed by yeast cell was studied using acetophenone, propiophenone, 4'-methylacetophenone and 4'-choloracetophenone as substrates. The influences of additive β-cyclodextrin and hydroxypropyl-β-cyclodextrin on asymmetric reduction of aromatic ketones were also investigated respectively. The results show that the conversion rate and the enantiomeric excess value were markedly affected by both steric effect and electronic effect of substituted group. The reaction results were affected by cyclodextrions through enhancing the catalytic efficiency of yeast fermentation broth and inclusion with the substrate, among which p-substituted group of the substrate aromatic cycle is the key factor. Suitable amount of joined cyclodextrins is 3~10 mmol/L according as different substrates." @default.
- W2364658905 created "2016-06-24" @default.
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- W2364658905 date "2008-01-01" @default.
- W2364658905 modified "2023-09-23" @default.
- W2364658905 title "Asymmetric Reduction of Aromatic Ketones by Yeast Cells Catalyzed in the Presence of Cyclodextrins" @default.
- W2364658905 hasPublicationYear "2008" @default.
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