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- W2364686971 abstract "The nitrite-selective PVC membrane electrodes prepared with lipophilic long-chain tetraal- kyltin compounds as neutral carrier show selectivity patterns significantly different from those obtained with classical anion-exchangers. The potentiometric selectivity coefficient for nitrite ion with respect to nitrate ion has been improved by about four orders of magnitude. The linear response range of the electrode based on tetralauryltin (TLT) is from 1×10~(-1)M down to 2×10~(-5)M with a detection limit of 5×10~(-6)M. The Nernstian response of the electrode in the medium of pH≥7 gradually changes to a doubled super-Nernstian response when the solution turns slightly acidic. The change of the response slope has a closely relation with the stepwise complex-formation equilibrium of the carrier with the anion involved, which was experimentally studied by using ultraviolet spectroscopy. An explanation of the anomalous response behavior as well as the curve form of the potential-pH plot is given." @default.
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- W2364686971 date "1988-01-01" @default.
- W2364686971 modified "2023-09-24" @default.
- W2364686971 title "Long-chain tetraalkyltin compounds as neutral carriers for nitrite-selective PVC membrane electrodes" @default.
- W2364686971 hasPublicationYear "1988" @default.
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