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- W2364695381 abstract "The intrinsic kinetics of new cobalt molybdenum sulfur-tolerant catalyst for shift reaction was studied in an isothermal integral tubular reactor under the reaction condition of temperature(550-750) K,pressure(2.0-3.5) MPa and space velocity(15-30) L·(g·h)-1.The intrinsic kinetics model taking the form of power function which included the pressure was built as follows: r=-dNCO dW=39981.876exp(-68424.0 RT) P0.4176COP0.9297H2OP-0.5516CO2P-0.7503H2(1-β).Using particle swarm optimization and Runge-Kutta algorithm,the parameters in the kinetics model were fit to the experimental data.The accuracy and the correlating degree of experimental data and calculated model were verified by F-test and correlation index test.The results showed that the reaction rate was not sensitive to pressure change of CO component but was sensitive to the pressure of H2O component.High catalytic activity was obtained under high steam gas ratio." @default.
- W2364695381 created "2016-06-24" @default.
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- W2364695381 date "2013-01-01" @default.
- W2364695381 modified "2023-09-25" @default.
- W2364695381 title "Intrinsic kinetics of a new cobalt molybdenum sulfur-tolerant shift catalyst" @default.
- W2364695381 hasPublicationYear "2013" @default.
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