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- W2364784946 abstract "The relationship of the amounts of emulsifier,organosilicon monomer octamethylcyclotetrasiloxane(D_4) and initiator(KPS) with the ratio of fluorescence intensity between first vibronic peak of pyrene(λ= 373 nm) and third vibronic peak of pyrene(λ=384 nm) I_1/I_3 was discussed during the emulsion polymerization process,in which pyrene was used as a fluorescence probe.The polymerization behavior of the organosilicon-acrylate latex with core-shell structure was investigated on line with the relationship of monomer conversion and development of morphology in latex particles with the value of I_1/I_3 for probe pyrene during the polymerization process.It showed that the values of I_1/I_3 for probe pyrene changed with changing the amounts of emulsifier, D_4,KPS and increased with increasing the monomer conversion.A good performance emulsion was obtained while the amounts of emulsifier,D_4,mass ratio between KPS and the whole monomer was 2 g,(8 g) and 0.7%,respectively.The values of I_1/I_3 for probe pyrene also changed obviously when the morphology of latex particles transformed from seeded latex particles into core-shell latex particles during the polymerization process.That means the organosilicon-acrylate latex with core-shell structure exhibits an interpenetrating polymer network(IPN) structure.Therefore,fluorescence probe technique can be used to study the progress of the polymerization behavior of organosilion-acrylate latex with core-shell structure." @default.
- W2364784946 created "2016-06-24" @default.
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- W2364784946 date "2010-01-01" @default.
- W2364784946 modified "2023-09-25" @default.
- W2364784946 title "STUDEIS ON POLYMERIZATION BEHAVIOR OF ORGANOSILICON-ACRYLATE LATEX WITH CORE-SHELL STRUCTURE USING FLUORESCENCE PROBE TECHNIQUE" @default.
- W2364784946 hasPublicationYear "2010" @default.
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