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- W2364793073 abstract "The crystal and molecular structures of the K4[InⅢ(cydta)(H2O)]4·14H2O(cydta = trans-1,2-cydohexanediaminetetraacetic acid) complex has been determined by single-crystal X-ray structure analysis.The crystal of the K4[InⅢ(cydta)(H2O)]4·14H2O complex belongs to monoclinic crystal system and P2(1)/c space group.The crystal data are as follows:a=1.4460(3) nm,b=3.5530(7) nm,c=1.6290(3) nm,β=90.21(3).,V=8.369(3) nm3,Z=4,M=2228.93,Dc=1.769 g·cm-3,μ=1.391 mm-1 and F(000) =4464.The final R and wR values are 0.0631 and 0.2786 for 14708 [I2.0σ(Ⅰ)] reflections,and 0.1631 and 0.2786 for all 15331 unique reflections,respectively.The total complex molecule is composed of four close parts in structure.The every part around the InⅢ ion in the [InⅢ(cydta)(H2O)]-complex anion has a seven-coordinate structure with distorted monocapped trigonal-prism,in which the cydta as a hexadentate ligand coordinates to the central InⅢ ion with two N atoms and four O atoms,in addition,a water molecule directly coordinate to the central InIII ion as the seventh ligand also." @default.
- W2364793073 created "2016-06-24" @default.
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- W2364793073 date "2007-01-01" @default.
- W2364793073 modified "2023-09-23" @default.
- W2364793073 title "Synthesis and structure of two-dimension tetranuclear seven-coordinate K_4[n~III(cydta)(H_2O)]_4·14H_2O complex" @default.
- W2364793073 hasPublicationYear "2007" @default.
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