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- W2364862097 abstract "The effects of 0.5% Pt/γ-Al2O3 catalysts with different K promoters for preparing o-phenylphenol(OPP) from o-cyclohexenylcyclohexanone dehydrogenation were studied.These catalysts were characterized by XRD,H2-TPD,NH3-TPD,CO2-TPD techniques.The results showed that the addition of K decreased the acidity,basicity and the volume of absorbed hydrogen.The 6.00%K2SO4 promoter weakened the acid-base strength and decreased the acid-base sites.It also adjusted the adsorption of intermediate products,OPP and volume of hydrogen,prohibited the formation of byproducts,and obviously improved the selectivity of OPP.The conversion of o-cyclohexenylcyclohexanone reached 100% and the selectivity of o-phenylphenol was more than 90% with 0.12 h-1 of LHSV and 33 ml·g-1·h-1 H2 flow rate at 380℃." @default.
- W2364862097 created "2016-06-24" @default.
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- W2364862097 date "2008-01-01" @default.
- W2364862097 modified "2023-09-27" @default.
- W2364862097 title "Promotive effect of potassium on Pt/γ-Al_2O_3 catalyst for preparing o-phenylphenol" @default.
- W2364862097 hasPublicationYear "2008" @default.
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