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- W2365086613 abstract "Waterborne Polyurethane(urea)/polyacrylate (PU(U)A) dispersion was synthesized from 1 - iso-cyanato -3,3,5 - trimethyl - 5 - isocyanato - methyl - cyclohexane, dimethylol propionic acid, polyester polyol ( Mn = 2000g/mol, f = 2 ) , ethyldiamine, diethanol amine, methyl methacylate, butyl acrylate and hydroxyethyl methacrylate by using the in - situ polymerization, and PU ( U) A/SiO2 hybrid dispersion was obtained then by using the sol - gel process. The storage time of the hybrid dispersion was more than one year at pH 7 - 11. Its heat stability, freeze - thaw stability was just the same of PU (U ) A dispersion. The properties of the hybrid film, including hardness, adhesion, absorption of water and solvent resistance were better than those of the film without SiO2. TEM photograph of the PU ( U) A/SiO2 hybrid dispersion showed that the PU (U)A particles with the diameter of 50 -200nm was surrounded by silica particles with the diameter of 8 -10nm. ART - FTIR showed that the Si - 0 - Si groups enriched on the surface of the hybrid film. AFM revealed that, compared with the surface of PU(U) A film, the size of hard domains became smaller." @default.
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- W2365086613 date "2005-01-01" @default.
- W2365086613 modified "2023-09-24" @default.
- W2365086613 title "The study of Pu(u) A/SiO_2 hybrid water dispersions and films" @default.
- W2365086613 hasPublicationYear "2005" @default.
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