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- W2365388086 abstract "A new complex [Co(NIT-1′-MeBzIm)2Cl2](NIT-1′-MeBzIm = 2-{2′-[(l′-methyl)-benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and structurally characterized by X-ray diffraction method.The complex crystallizes in the monoclinic system,space group C2/c,Z = 4.Crystal data:C30H38Cl2CoN8O4,Mr = 704.51,a = 17.074(3),b = 21.350(3),c = 11.6962(19),β = 108.879(2)°,V = 4034.3(11)3,Dc = 1.160 g/cm3,μ(MoKα) = 0.597 mm-1,F(000) = 1468,R = 0.0422 and wR = 0.1141 for 2577 observed reflections with I 2σ(I).X-ray analysis reveals that the Co(Ⅱ) ion is six-coordinated with a distorted octahedral geometry.Temperature dependence of susceptibility measurements shows the existence of antiferromagnetic interactions between the Co(Ⅱ) ion and the radicals(J =-52.88 cm-1)." @default.
- W2365388086 created "2016-06-24" @default.
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- W2365388086 date "2011-01-01" @default.
- W2365388086 modified "2023-09-25" @default.
- W2365388086 title "Synthesis,Crystal Structure and Magnetic Properties of a Co(II) Complex Containing 2′-(l′-Methyl)benzimidazolyl-substituted Nitronyl Nitroxide" @default.
- W2365388086 hasPublicationYear "2011" @default.
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