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- W2365481421 abstract "A key intermediate,trifluoromethyl substituted( S)-tert-butylsulfonylamide( 3),was prepared by addition reaction of 2-methylindole with α-trifluoromethylaldimine under basic condition.The yield and stereoselectivity of 3 were 95% and 99 /1.( S)-2,2,2-trifluoro-1-( 2-methyl-1H-indol-1-yl) ethanamine( 4) with yield of 97% was synthesized by removing of the protection group of 3. The structure was confirmed by1 H NMR,13 C NMR,19 F NMR,FT-IR,EI-MS and HR-EI-MS." @default.
- W2365481421 created "2016-06-24" @default.
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- W2365481421 date "2015-01-01" @default.
- W2365481421 modified "2023-09-24" @default.
- W2365481421 title "Asymmetric Synthesis of (S)-2,2,2-trifluoro-1-( 2-methyl-1H-indol-1-yl) ethanamine" @default.
- W2365481421 hasPublicationYear "2015" @default.
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