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- W2365725135 abstract "The samples of nylon-64 that prepared under supercritical CO2 are investigated by differential scanning calorimetry(DSC). And its nonisothermal crystallization kinetics is studied using the Avrami equations modified by Jeziomy and Mo. Some important kinetics parameters are calculated and obtained. The results attained by Jeziorny method show that the nonisothermal crystallization kinetics of nylon64 includes two stages,in main crystallization stage,when the cooling rate under 10℃/min,the Avrami index (n) between 3.59 and 4.12,which show most of the nucleations process are homogeneous and the three dimension growth of the crystal particles. And the growth of the crystal particles is restricted when the cooling rate exceeds 10℃/min. In the inferior crystallization stage,most of the growth of the crystal particles are the one dimension.The a value obtained by Mo method is from 1.26 to 1.33,and the F(T) is from 6.35 to 13.02. In addition,the activation energy of nonisothermal crystallization for nylon-64 obtained by Kissinger method and Takhor method are-192.05kJ/mol and-176.21kJ/mol,respectively." @default.
- W2365725135 created "2016-06-24" @default.
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- W2365725135 date "2010-01-01" @default.
- W2365725135 modified "2023-09-23" @default.
- W2365725135 title "Study on Nonisothermal Crystallization Kinetics of Nylon-64" @default.
- W2365725135 hasPublicationYear "2010" @default.
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