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- W2366172373 abstract "The average instantaneous shape of polyethylene chain with excluded volume was studied with Monte Carlo method. The short range interactions of the chain are considered approximately as third order interactions, while long range interactions are excluded volumes of skeleton atoms. 〈L 2 2〉/〈L 1 2〉 and 〈L 3 2〉/〈L 1 2〉 of polyethylene chain with excluded volumes are much bigger than that of polyethylene chain without excluded volumes. The limit value of the ratio 〈L 1 2〉∶〈L 2 2〉∶〈L 3 2〉 of polyethylene chain with excluded volumes, extrapolated from the datum of chain length around N =400, is about 1∶3.0∶14.5, while that of polyethylene chain without excluded volumes is about 1∶2.7∶12.0. The angle θ between the longest principal axis of inertia of the polyethylene chain with excluded volumes and the end to end vector was also investigated, which statistical average 〈 θ 〉 is about 25° for long chain." @default.
- W2366172373 created "2016-06-24" @default.
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- W2366172373 date "2000-01-01" @default.
- W2366172373 modified "2023-09-25" @default.
- W2366172373 title "Influence of Excluded Volume on the Shape of Polyethylene Chain" @default.
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