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- W2366570654 abstract "Two metal complexes 1 ([Cu(L1)] 2+) and 2 ([Cu(L2)] 2+) based on Schiff base were synthesized and studied as anion-binding receptors in polar solvent such as V(H 2O)∶V(Ethanol)=98∶2 mixture. The results indicated that the metal complex 1 with a C 3v symmetric cavity could act as efficient and selective reagents for PO 3- 4. The UV-vis spectroscopic titration experiments indicated the formation of 1∶1 stable complexes between 1 and PO 3- 4. In addition, complex 1 has also a little response to HPO 2- 4, but there are no any responses to other anions such as non-tetrahedron type anions and tetrahedron type anions. The binding manner and possible structure formed between the complex 1 and PO 3- 4 were proposed. The experimental results and some consideration concerned to improve the selectivity of sensor on design were discussed preliminarily." @default.
- W2366570654 created "2016-06-24" @default.
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- W2366570654 date "2004-01-01" @default.
- W2366570654 modified "2023-09-23" @default.
- W2366570654 title "A Metal-containing Chemosensor for Selective Recognition of Phosphate Anion in Water" @default.
- W2366570654 hasPublicationYear "2004" @default.
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