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- W2367713158 abstract "A series of tetracarboxylic metal phthalocyanines are synthesized and their electronic absorption spectra are investigated.There are several factors influence the maximum absorption wavelength λmax of Q band: the electronic structure of central metal atom;peripheral substituents;polarity of the solvent in which it dissolves.The results depict that if the d-shell of the metal atom is not full,λ_(max) value increases directly with eletronagativity of the central atom and change inversely with the atomic radius;if the d-shell of the metal atom is full the results are inversed compared with λ_(max) value of the former.The λ_(max) value of Q-band shifts to the red owing to the carboxyl groups on the phthalocyanine ring.Moreover,the λ_(max) value of the compounds closely depends on polarity of the solvent,in the result that the λ_(max) value of the compounds gradually moves to the red with the increasing of the polarity of solvent." @default.
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- W2367713158 date "2006-01-01" @default.
- W2367713158 modified "2023-09-25" @default.
- W2367713158 title "Electronic absorption spectra of tetracarboxylic metal phthalocyanines" @default.
- W2367713158 hasPublicationYear "2006" @default.
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