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- W2367745820 abstract "Polymerization of octodecyl acrylate in four solvents carbon tetrachloride, chloroform, methylbenzene and tetrachloroethane were studied on the influence factors of polymerization and the molecular weight of polyoctodecyl acrylate. Experimental results indicated that the sequence of chain transfer constants in solvents was arranged as carbon tetrachloride chloroform methylbenzene tetrachloroethane in the polymerization of octodecyl acrylate. Influences of four solvents on solubility of polyoctodecyl acrylate were not the same. In chloroform, polyoctodecyl acrylate showed the highest relative viscosity and the lowest chain stop constant. With the increase of monomer conversion, the least reduction in its molecular weight of polyoctodecyl acrylate was observed. At higher conversions, the molecular weight of polyoctodecyl acrylate was mainly influenced by the chain transfer constant. Under the circumstances of monomer conversion higher than 30%, the molecular weight of polyoctodecyl acrylate in methylbenzene was higher than that in tetrachloroethane. The solubility of polyoctodecyl acrylate in methylbenzene was better than that in tetrachloethane, and the influence of gelation on the average molecular weight of polyoctodecyl acrylate was stronger than that of chain transfer in solvents." @default.
- W2367745820 created "2016-06-24" @default.
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- W2367745820 date "2001-01-01" @default.
- W2367745820 modified "2023-09-30" @default.
- W2367745820 title "INFLUENCE OF SOLVENTS ON POLYMERIZATION OF OCTODECYL ACRYLATE" @default.
- W2367745820 hasPublicationYear "2001" @default.
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