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- W2367857243 abstract "In this paper the kinetic characteristics of the quaternization of poly-p-chloromethyl sty-rene (P-pCMS) are explored. It has shown that the quaternization'of P-pCMS with triethyla-mine (TEA), tributylamine (TBA), and pyridine all conform with the kinetic equation for second order reactions, i.e., they are second order reaction. The activity sequence of the ter-tiaryamines examined is as follows: triethylaminetributylamine pyridine 3N N-dimethyl-aniline, p-bromo-N, N-dimethyl-aniline, ia which the activation energy of the former three is 12.92, 14.57, and 19.13 Kcal/mol respectively and the latter two only show negligible activity even at 80℃. This sequence of activity is consistant with the pKb values of these tertiary amine." @default.
- W2367857243 created "2016-06-24" @default.
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- W2367857243 date "1990-01-01" @default.
- W2367857243 modified "2023-09-23" @default.
- W2367857243 title "STUDIES ON THE QUATERNIZATION OF POLY-P-CHLOROMETHYL STYRENE" @default.
- W2367857243 hasPublicationYear "1990" @default.
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