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- W2368018596 abstract "Bench scale of photcooxidation plutonium(Ⅲ)of 1BP to plutonium(Ⅳ)in Purex processinstead of adding sedium nitrite has been achieved by UV Iight irradiation. The alternative tech-nology can realize so-called solt-free process. The about 99%of plutonium(Ⅲ) is oxidized to plu-tonium(Ⅳ) at 7.5h,but plutonium(Ⅵ)is less than 1%,extending 2.5h of irradiation,less than7%plutonium(Ⅵ)can be controled.The effects of concentration of plutonium ,nitric acid andferrous ion and of power of light source and of temperature on photooxidation of plutonium(Ⅲ)have been investegated.The results show that,in the constant conditions of concentration of fer-rous ion and hydrazine,changing concentration of plutonium from 0.30,0.66 to 1.14g/1,concen-tration of nitric acid from 1.5 to 2.7 mol/l,the photcoxidation of plutonium(Ⅲ) is not effected.In the same conditions,the time of photcoxidation of plutonium(Ⅲ)decreases with the increaseof power of light source and with increase of temperature. In addition,the effects of keeping timeof solution irradiated on the change of valence of plutonium have been observed. The results showthat the valence of plutonium dose not change in ten days." @default.
- W2368018596 created "2016-06-24" @default.
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- W2368018596 date "1995-01-01" @default.
- W2368018596 modified "2023-09-24" @default.
- W2368018596 title "STUDY ON PHOTOOXIDATION OF PLUT0NIUM(III)0F 1BP IN PUREX PROCESS" @default.
- W2368018596 hasPublicationYear "1995" @default.
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