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- W2368091901 abstract "Cucurbit[n]urils which are potentially as useful the as well-known host molecules such as crown ethers and cyclodextrins(CDs) have been an important part of supermolecule field in these years.Their host-guest chemistry as well as supramolecular assemblies based on Q[n] has been studied and summarized widely.However,the poor solubility in common solvents and the hard separation have limited the development of the chemistry of cucurbit[n]uril.Thus,synthesis and separation Q[n] derivatives,which allow them to dissolve in both aqueous systems and common organic solvents,have received great attention.The mixture methyl substituted cucurbit[n] urils(n=5,6,7) [di-methyl substituted cucurbit[5]uril(DiMe-Q[5])、the tetrad-methyl substituted cucurbit[6]uril(TMe-Q[6])and the di-methyl substituted cucurbit[7]uril(DiMe-Q[7])] was Optimum Synthesis by using the diether of dimethylglycoluril and the dimer of glycoluril in this paper.The results of 1HNMR spectroscope proved that the DiMe-Q[5]、the TMe-Q[6] and the DiMe-Q[7] could be separated completely by the chromatographer." @default.
- W2368091901 created "2016-06-24" @default.
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- W2368091901 date "2008-01-01" @default.
- W2368091901 modified "2023-09-23" @default.
- W2368091901 title "Studied on the Optimum Synthesis Way and Separation of the Methyl Substituted Cucurbit[n]urils" @default.
- W2368091901 hasPublicationYear "2008" @default.
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