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- W2368364090 abstract "The fluorocarbanion [n-C_3F_7OCF (CF_3)~-] generated by decarbomethoxylation of methyl perfluoro-2-methyl-3-oxa-hexanoate(1)can be trapped in many cases with substituted benzoyl chlorides (YArCOCl). In this way, a simple, convenient method for the preparation of aryl β-oxa-fluoroalkyl- ketones has been developed, The mechanistic consideration of the ester decomposition induced by the lithium chloride/hexamethylphosphoric triamide complex (LiCl/HMPA) and KI/CH_2CN involves nucleophilic attack by halides on the methoxy carbon of the ester 1." @default.
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- W2368364090 date "1986-01-01" @default.
- W2368364090 modified "2023-09-23" @default.
- W2368364090 title "A new method for the preparation of aryl perfluoro-1-methyl-2-oxa-pentyl ketones" @default.
- W2368364090 hasPublicationYear "1986" @default.
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