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- W2368419323 abstract "TSEPIP-C8 derivative was prepared based on the derivatization of caprylic(C8) acid using 1-[2-(p-toluenesulfonate)ethyl]-2-phenylimidazole[4,5-f]9,10-phenanthrene(TSEPIP) as the derivatization reagent by pre-column derivatization and solid phase extraction(SPE).Fluorescence spectra properties of TSEPIP-C8,at different solvent polarity,temperature and in the presence of different halide salts and heavy metal atoms,were studied on fluorescence spectrophotometer,which provided dependence for HPLC analysis with fluorescence detection.Separation of 26 types of derivatized fatty acids(C1-C26) was carried out at the detection wavelength 380 nm with a good baseline resolution in conjunction with a gradient elution on a reversed-phase Eclipse XDB-C8 column.By this procedure,the contents of free fatty acids in Salvia miltiorrhiza B.were determined.The simple and convenient identification of fatty acid derivatives was carried out by post-column tandem mass spectrometry with atmospheric-pressure chemical ionization(APCI) source in a positive ion mode.Excellent linear responses were observed with correlation coefficients 0.999 6,and the detection limits were 3.824~47.13 fmol(injection volume 10 μL,at signal-to-noise of 3:1)." @default.
- W2368419323 created "2016-06-24" @default.
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- W2368419323 date "2007-01-01" @default.
- W2368419323 modified "2023-09-28" @default.
- W2368419323 title "Preparation of caprylic TSEPIP derivative and its fluorescence spectra study and application for HPLC analysis" @default.
- W2368419323 hasPublicationYear "2007" @default.
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