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- W2368752026 abstract "The series of porous magnets of [M_3(HCOO)_6](M=Mn~(2+),Fe~(2+),Co~(2+),Ni~(2+),Fe~(2+)/Zn~(2+)) can be prepared by conventional solution chemistry method.They possess open diamond framework based on M-centred MM4 tetrahedral nodes,and display permanent porosity,stability for thermal treatment,guest removal,and guest inclusion for a wide spectrum of guests of different size and property.The porous magnets show 3D long-range magnetic ordering and guest-modulated magnetism due to the subtle structure change of the magnetic framework that conforms to the guests and the host-guest interaction.The dilution of [Fe3(HCOO)6] framework by diamagnetic zinc ion results in a series of mixed-metal porous magnets of [FexZn3-x(HCOO)6] showing gradual evolution from 3D long-range ordering to spin glass then superparamagnetism and finally paramagnetism." @default.
- W2368752026 created "2016-06-24" @default.
- W2368752026 creator A5035348848 @default.
- W2368752026 date "2008-01-01" @default.
- W2368752026 modified "2023-09-25" @default.
- W2368752026 title "The study on porous magnets [M_3(HCOO)_6](M=Mn~(2+),Fe~(2+),Co~(2+),Ni~(2+),Fe~(2+)/Zn~(2+))" @default.
- W2368752026 hasPublicationYear "2008" @default.
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