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- W2368771778 abstract "Using substitution method, the Pd, Ir, Ru noble metal substituted polyoxomolybdates with the general formula α (n Bu 4N) n XMo 11 M(H 2O)O 39 (X=Si,Ge;M=Pd(Ⅱ), Ru(Ⅲ), Ir(Ⅳ)) have been prepared. The measurements of IR, UV and EPR show that the products still remain the Keggin type structure of their parental compound, and the cation of noble metal Pd or Ir or Ru does substitute one Mo of the parental compound. Electrochemical study shows that after Ir substitutes one Mo of the parental compound, the redox reversitbility of the polyacid parent is improved, but the electrochemical behavior of Pd substituted compound can not be observed clearly because of its adsorption on electrode. The preliminary catalytic studies of the compounds mentioned above show that all these substituted polyoxomolybdates have fairly good catalytic activities for the cyclohexene epoxidation reaction." @default.
- W2368771778 created "2016-06-24" @default.
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- W2368771778 date "2000-01-01" @default.
- W2368771778 modified "2023-09-25" @default.
- W2368771778 title "Preparation, Characterization and Preliminary Catalytic Studies of Six Noble-Metal-Substituted Polyoxomolybdates" @default.
- W2368771778 hasPublicationYear "2000" @default.
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