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- W2368803941 abstract "RAFT equilibrium constant K is the key factor to the dispersion stability of emulsion polymerization and kinetics.Therefore,at the same concentration of RAFT agent,the K values of two types with 4.06 L/(mol·s) and 314 L/(mol·s) are engaged in the styrene RAFT miniemulsion polymerization.Then their effects of on the polymerization kinetics are evaluated.It is found that the PSD of the final latex is little effected by the variation of the RAFT agents with different K values.Though the retardation is neglected in the experiment with low-K value RAFT agent,the PDI of the final products is as high as 3.68.A different case is found for the one using RAFT agent with high-K value that the rate is seriously retarded,but the PDI was only 1.51 when the Mn grew to 6×104 g·mol-1 finally.It is far superior to those of low-K value RAFT agent." @default.
- W2368803941 created "2016-06-24" @default.
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- W2368803941 date "2011-01-01" @default.
- W2368803941 modified "2023-09-25" @default.
- W2368803941 title "RAFT Equilibrium Constant on the Impact of RAFT Miniemulsion Polymerization" @default.
- W2368803941 hasPublicationYear "2011" @default.
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